化學與生命健康交叉研究中心

陰國印
時間:2020-04-05 08:44:58點擊量:

 

武漢大學高等研究院特聘研究員,博士生導師

地址:湖北省武漢市武昌區八一路299號,郵編:430072

郵箱:yinguoyin@whu.edu.cn

 

主要研究方向:合成化學、金屬催化

1. 涉及金屬遷移的轉化反應研究:從簡單原料出發, 設計與探索涉及金屬遷移的轉化催化,合成有價值的化合物。

2. 催化反應機理研究:利用物理有機化學的方法以及理論計算化學等對催化反應的機理進行詳細研究

 

教育背景

2006.9– 2011.7 理學博士(有機化學)

中科院上海有機化學研究所,金屬有機國家重點實驗室 導師:劉國生 研究員

2002.9 – 2006.7 理學學士(應用化學)

東北農業大學,理學院

 

工作經歷

2016.08--至今 特聘研究員、博士生導師 武漢大學高等研究院

2016.8–2014.11 博士后研究員 美國特拉華大學

合作導師:Donald A. Watson 教授

2013.9–2014.9 博士后研究員 德國亞琛工業大學

合作導師:Franziska Schoenebeck教授

2011.11-2013.07 德國洪堡學者、博士后研究員 德國慕尼黑工業大學

合作導師:Thorsten Bach教授、院士

 

榮譽和獎勵

2017    Thieme Chemistry Journal Award      

2014 中國科學院優秀博士學位論文

2011 德國洪堡獎學金

2009 中國科學院三好學生

2009 上海有機所葛蘭素史克獎學金

2008 中國科學院三好學生

 

獨立工作之后發表論文:

20. Catalyst-Controlled Enantioselective 1,1-Arylboration of Unactivated Olefins. Wang Wang, Chao Ding and Guoyin Yin*. Nat. Catal., 2020, Accepted manuscript.

 

19. Synergistic Ni/Cu Catalyzed Migratory Arylsilylation of Terminal Olefins. Binzhi Zhao, Yuqiang Li, Haoyang Li, Md. Belal, Lei Zhu* and Guoyin Yin*. Sci. Bull., 2020, Accepted manuscript.

 

18. Nickel-Catalyzed Migratory Alkyl-Alkyl Cross-Coupling Reaction. Yangyang Li, Yuqiang Li, Long Peng, Dong Wu Lei Zhu* and Guoyin Yin*. Chemical Science. 2020. doi: 10.1039/d0sc03217d.

 

17. Nickel-Catalyzed Three-Component Asymmetric Fluoroalkylarylation of Unactivated Olefins. Hong Wei and Guoyin Yin*. Chin. J. Org. Chem. 2020, doi: 10.6023/cjoc202006035.

16. Palladium-Catalyzed Stereoselective 1,3-Diarylation of 1,4-Cyclohexadiene. Hailiang Pang, Dong Wu and Guoyin Yin*. Chin. J. Org. Chem. 2020, doi: 10.6023/cjoc202006022.

15. Modular Synthesis of Diarylalkanes by Nickel-Catalyzed 1,1-Diarylation of Unactivated Terminal Alkenes. Zheqi Li, Dong Wu, Chao Ding, Guoyin Yin*. CCS Chem. 2020, 2, 576-582.

 

 

14. Yuqiang Li, Yixin Luo, Yu Lan* and Guoyin Yin*. Reaction scope and mechanistic insights of nickel-catalyzed migratory Suzuki–Miyaura cross-coupling. Synform 2020, 05, A73-A74.

 

13. Difunctionalization of Alkenes Involving Metal Migration. Yuqiang Li, Dong Wu, Hong-Gang Cheng*, Guoyin Yin*. Angew. Chem., Int. Ed. 2020, 59, 7990-8003.

 

12. Nickel-Catalyzed Chemodivergent 1,1-Difunctionalization of Unactivated alpha-Olefins with Alkynyl Electrophiles and B2pin2. Yangyang Li, Hong Wei, Dong Wu, Zheqi Li, Wang Wang, and Guoyin Yin*. ACS Catal. 2020, 10, 4888?4894.

 

11. Aminoazanium of Triethylenediamine: a General and Practical Amination Reagent for Alkyl and Aryl Pinacol Boronates. Haoyang Li, Guoyin Yin*. Chin. J. Org. Chem. 2020, 40, 547-548.

 

10. Reaction Scope and Mechanistic Insights of Nickel-Catalyzed Migratory Suzuki–Miyaura Cross-Coupling. Yuqiang Li, Yixin Luo, Long Peng, Yangyang Li, Binzhi Zhao, Wang Wang, Hailiang Pang, Yi Deng, Ruopeng Bai, Yu Lan* and Guoyin Yin*. Nat. Commun. 2020, 11, 417.

 

9. Nickel/Br?nsted Acid-Catalyzed Chemo- and Enantioselective Intermolecular Hydroamination of Conjugated Dienes. Jiao Long, Peng Wang, Wang Wang, Yuqiang Li, Guoyin Yin*. iScience, 2019, 22, 369-379.

 

8. Nickel-Catalyzed Migratory Arylboration of Nonactivated Alkenes. Wang Wang, Chao Ding, Guoyin Yin*. (Wang Wang and Chao Ding contribute equally). Synlett 2019, 30, 1850-1854.

7. Stereoselective Palladium-Catalyzed 1,3-Arylboration of Unconjugated Dienes for Expedient Synthesis of 1,3-Disubstituted Cyclohexanes. Hailiang Pang, Dong Wu, Hengjiang Cong, Guoyin Yin*. ACS Catal., 2019, 9, 8555–8560.

 

6. Nickel-Catalyzed 1,1-Alkylboration of Electronically Unbiased Terminal Alkenes. Yangyang Li, Hailiang Pang, Dong Wu, Zheqi Li, Wang Wang, Hong Wei, Ying Fu, Guoyin Yin*. Angew. Chem. Int. Ed., 2019, 58, 8872-8876.

 

5. Nickel-Catalyzed 1,2-Arylboration of Vinylarenes. Wang Wang, Chao Ding, Hailiang Pang, Guoyin Yin*. Org. Lett. 2019, 21, 396 -3971. 

4. Nucleophilic α-Fluorination of Amides. Hong-Gang Cheng, Guoyin Yin*. Chem., 2019, 5, 1022-1024.

3. Migratory Arylboration of Unactivated Alkenes Enabled by Nickel Catalysis. Wang. Wang, Chao Ding, Yangyang Li, Zheqi Li, Yuqiang Li, Long Peng, Guoyin Yin*. Angew. Chem. Int. Ed. 2019, 58, 4612-4616.

 

2. Photochemical Nickel-Catalyzed Reductive Migratory Cross-Coupling of Alkyl Bromides with Aryl Bromides. Long Peng, Zheqi Li and Guoyin Yin*. Org. Lett., 2018, 20, 1880-1883.

 

1. Ligand-Controlled Nickel-Catalyzed Reductive Relay Cross-Coupling of Alkyl Bromides and Aryl Bromides. Long Peng, Yuqiang Li, Yangyang Li, Wang Wang, Hailiang Pang and Guoyin Yin*. ACS Catal., 2018, 8, 310–313.

 

博士與博士后期間:

1.   Guoyin Yin, Guosheng Liu*, Palladium-Catalyzed Oxidative Cyclization of Enynes with Hydrogen Peroxide as the Oxidant. Angew. Chem. Int. Ed. 2008, 47, 5442-5445. (Featured in Synfact, 2008, 10, 1066)

 

2.   Guosheng Liu*, Guoyin Yin, Liang Wu, Palladium-Catalyzed Intermolecular Aerobic Oxidative Amination of Terminal Alkenes: Efficient Synthesis of Linear Allylamine Derivatives. Angew. Chem. Int. Ed. 2008, 47, 4733- 4736.

 

3.  Tao Wu, Guoyin Yin, Guosheng Liu*, Palladium-Catalyzed Intramolecular Aaminofluorination of Unactivated Alkenes. J. Am. Chem. Soc. 2009, 131, 16354-16355.

 

4.   Guoyin Yin, Yichen Wu, Guosheng Liu*, Scope and Mechanism of Allylic C?H Amination of Terminal Alkenes by the Palladium/PhI(OPiv)2 Catalyst System: Insights into the Effect of Naphthoquinone. J. Am. Chem. Soc. 2010, 132, 11978-11987.

 

5.   Guoyin Yin, Tao Wu, Guosheng Liu*, Highly Selective Palladium-Catalyzed Intramolecular Chloroamination of Unactivated Alkenes by Using Hydrogen Peroxide as an Oxidant. Chem. Eur. J. 2012, 18, 451-455.

 

6.   Guoyin Yin, Eberhardt Herdtweck, Thorsen Bach*, Enantioselective Access to Bicyclo[4.2.0] octanes by a Sequence of [2+2] Photocycloaddition/ Reduction/Fragmentation. Chem. Eur. J. 2013, 19, 12639-12643.

 

7.   Guoyin Yin, Indrek Kalvet, Ulli Englert, Franziska Schoenebeck*, Fundermental Studies and Development of Nickel-CatalyzedTrifluoromethylthiolation of Aryl Chlorides: Active Catalytic Speciesand Key Roles of Ligand and Traceless MeCN Additive Revealed. J. Am. Chem. Soc. 2015.137, 4164-4172.

 

8.   Guoyin Yin, Indrek Kalvet, Franziska Schoenebeck*, Trifluoromethyl-thiolation of Aryl Iodides and Bromides Enabled by a Bench-Stable and Easy-To-Recover Dinuclear Pd(I) Catalyst. Angew. Chem. Int. Ed. 2015, 54, 6809-6813.

 

9.  Alexander Durr#, Guoyin Yin#, Indrek Kalvet, Fran?ois Napoly, Franziska Schoenebeck*, Ni-Catalyzed Trifluoromethylthiolation of Aryl Triflates. Chem. Sci. 2016, 7, 1076-1081. (# contributed equally to this paper)

 

10.  Guoyin Yin, Xin Mu, Guosheng Liu*,Palladium(II)-Catalyzed Oxidative Difunctionalization of Alkenes: Bond Forming at a High-Valent Palladium Center. Acc. Chem. Res. 2016, 49, 2413-2423.

 

11.  Scott A. Shuler, Guoyin Yin, Sarah B. Krause, Caroline M. Vesper, Donald A. Watson* Synthesis of Secondary Unsaturated Lactams via an Aza-Heck Reaction. J. Am. Chem. Soc., 2016, 138, 13830–13833.

 

12.  Thomas Scattolin, Erdem Senol, Guoyin Yin, Qianqian Guo, Franziska Schoenebeck*, Site-Selective C-S Bond Formation at C-Br over C-OTf and C-Cl Enabled by an Air-Stable, Easily Recoverable, and Recyclable Palladium(I) Catalyst. Angew. Chem. Int. Ed. 2018, 57, 12425.




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